Liquid metal makes silicon crystals at record low temperatures
An electron microscope image shows the pure silicon crystals, generated with the new greener technique. |
A new
way of making crystalline silicon, developed by U-M researchers, could make
this crucial ingredient of computers and solar cells much cheaper and greener.
Silicon dioxide, or sand, makes up about 40 percent of Earth's crust, but the
industrial method for converting sand into crystalline silicon is expensive and
has a major environmental impact due to the extreme processing conditions.
"The
crystalline silicon in modern electronics is currently made through a series of
energy-intensive chemical reactions with temperatures in excess of 2,000
degrees Fahrenheit that produces a lot of carbon dioxide," said Stephen
Maldonado, professor of chemistry and applied physics.
Recently,
Maldonado and chemistry graduate students Junsi Gu and Eli Fahrenkrug
discovered a way to make silicon crystals directly at just 180 F, the internal
temperature of a cooked turkey. And they did it by taking advantage of a
phenomenon you can see right in your kitchen.
When
water is super-saturated with sugar, that sugar can spontaneously form
crystals, popularly known as rock candy.
"Instead
of water, we're using liquid metal, and instead of sugar, we're using
silicon," Maldonado said.
Maldonado
and colleagues made a solution containing silicon tetrachloride and layered it
over a liquid gallium electrode. Electrons from the metal converted the silicon
tetrachloride into raw silicon, which then dissolved into the liquid metal.
"The
liquid metal is the key aspect of our process," Maldonado said. "Many
solid metals can also deliver electrons that transform silicon tetrachloride
into disordered silicon, but only metals like gallium can additionally serve as
liquids for silicon crystallization without additional heat."
The
researchers reported dark films of silicon crystals accumulating on the
surfaces of their liquid gallium electrodes. So far, the crystals are very
small, about 1/2000th of a millimeter in diameter, but Maldonado hopes to
improve the technique and make larger silicon crystals, tailored for
applications such as converting light energy to electricity or storing energy.
The team is exploring several variations on the process, including the use of
other low-melting-point metal alloys.
If the
approach proves viable, the implications could be huge, especially for the
solar energy industry. Crystalline silicon is presently the most-used solar
energy material, but the cost of silicon has driven many researchers to
actively seek alternative semiconductors.
"It's
too premature to estimate precisely how much the process could lower the price
of silicon, but the potential for a scalable, dramatically less expensive and
more environmentally benign process is there," Maldonado said. "The
dream ultimately is to go from sand to crystalline silicon in one step. There's
no fundamental law that says this can't be done."
The study, which appears in the Journal of the American Chemical Society, was
funded by the American Chemical Society Petroleum Research Fund.
The
university is pursuing patent protection for the intellectual property and is
seeking commercialization partners to help bring the technology to market.
Source: University
of Michigan
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Posted by Unknown
on Friday, January 25, 2013.
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